von Dr. Birgit Quack, GEOMAR Helmholtz-Zentrum für Ozeanforschung Kiel
Es gibt zwei Bereiche in unserer Atmosphäre, in denen das Spurengas Ozon besonders wichtig ist: in der Stratosphäre und in der Grenzschicht an der Erdoberfläche. In der oberen Region unserer Atmosphäre, der Stratosphäre, entsteht Ozon durch den Zerfall von Sauerstoff im Sonnenlicht und wirkt als wichtiger UV-Strahlenschutz für das Leben auf der Erde. Es wird durch Radikalreaktionen von Halogenen wie Chlor, Brom und Jod, die in verschiedenen Formen in unserer Atmosphäre vorkommen, rasch zerstört. In den 1980er Jahren trat ein großes Ozonloch auf, das mit den langlebigen Fluorchlorkohlenwasserstoffen in Verbindung gebracht werden konnte, die in den 1990er Jahren durch das Montrealer Protokoll verboten wurden. Seitdem nehmen das Ozonloch über der Antarktis und das Ozon in der oberen Stratosphäre im Allgemeinen langsam wieder zu. In der unteren Stratosphäre der Tropen nimmt es jedoch weiterhin ab. Das Oberflächenozon hingegen nimmt zu, was auf die Luftverschmutzung zurückzuführen ist, insbesondere auf die Verbrennung fossiler Brennstoffe.

Unter windy.com kann jeder weltweit, der Zugang zum Internet hat, eine globale Karte von Oberflächenozon und lokale Werte für jeden Ort der Welt finden (Abbildung 1). Oberflächenozon, das auch ein Treibhausgas ist, wird auf natürliche Weise bis zu einer Hintergrundkonzentration von 10-40 µg/m3 produziert. Da es ein starkes Oxidationsmittel ist, kann es in höheren Konzentrationen Augen und Lunge reizen. Für Städte, in denen die Umgebungskonzentrationen im Sommer über 100 µg/m3 ansteigen und empfindliche Menschen schädigen können, wurden gesetzliche Grenzwerte und Warnsysteme eingerichtet.
Abbildung 1 zeigt die Ozonkonzentration an der Oberfläche in dem Gebiet, in dem unsere Fahrt SO305 im Golf von Bengalen stattfand. Sie ist tagsüber über ganz Indien sehr hoch, und es ist auch offensichtlich, dass die Ozonkonzentrationen an den Küsten und zum offenen Ozean hin stark abnehmen. Dies ist hauptsächlich auf eine aktive Halogenchemie zurückzuführen, die das Ozon über den Ozeanen zerstört, verursacht durch natürliche halogenierte flüchtige Verbindungen, die in den Ozeanen durch Sonnenlicht, Phytoplankton und chemische Reaktionen gebildet werden. Zu diesen Verbindungen gehören Bromoform (CHBr3), Dibrommethan (CH2Br2), Methyljodid (CH3I), Dijodmethan (CH2I2), Jodchlormethan (CH2CII), Dichlorbrommethan (CHBrCl2) und andere. Sie gelangen in die Atmosphäre und setzen dort Halogene frei, die mit Ozon reagieren. Alle Verbindungen haben eine kurze Lebensdauer von Minuten bis zu weniger als sechs Monaten. Die industriellen Lösungsmittel Dichlormethan (CH2Cl2) und Chloroform (CHCl3) aus der Süßwasserchlorierung tragen ebenfalls zum Ozonabbau in der Atmosphäre bei. Die Verbindungen, die durch tiefe Konvektion in den Tropen in die Stratosphäre gehoben werden, setzen ihre Halogene in der unteren Stratosphäre frei, während sie sich zum Nord- und Südpol bewegen. So wirken sich die tropischen Prozesse global aus.
In den letzten vier Wochen waren wir nun im tropischen Golf von Bengalen, der 2001 als Hauptquelle für einige natürliche halogenierte flüchtige Verbindungen für die Atmosphäre entdeckt wurde, mit RV Sonne unterwegs.

Jule, die ihre Masterarbeit zu diesem Thema schreibt, Julia, die zum zweiten Mal als studentische Hilfskraft auf der RV Sonne mitfährt und ich, die seit über 30 Jahren auf den Weltmeeren flüchtige Halogenkohlenwasserstoffe untersucht, brachten unser Analysesystem mit an Bord, das seit Beginn der Fahrt rund um die Uhr in Schichten von jeweils 8 Stunden reibungslos lief, wobei das Gerät jede Stunde eine neue Probe erhält. Wir haben Wasser aus der Tiefsee und dem Oberflächenozean und Luft aus der Atmosphäre entnommen (Abbildung 3). Die Luftproben werden von Elliot Atlas in den USA analysiert, mit dem ich seit 2002 in 15 Kampagnen zusammengearbeitet habe. Aus den Konzentrationen im Ozean und in der Atmosphäre berechnen wir den Gasaustausch zwischen Luft und Meer, und versuchen zu verstehen, wie die Verbindungen in der Region mit physikalischen und biogeochemischen Parametern zusammenhängen, und schätzen ab, wie sich die ozeanische Quelle und Senke in Zukunft entwickeln könnten und was dies für Ozon als Treibhausgas und als UV-Schild bedeutet.
Bei jeder Schiffsexpedition in den 30 Jahren, in denen wir die Ozeane bereisten, erforschte ein Team von Wissenschaftlern und Crew an Bord verschiedener Forschungsschiffe den Ozean als ein uraltes Zusammenspiel von Wasser, Chemikalien, Billionen von Bakterien und höheren Organismen, das durch die Schwerkraft, die Erdrotation sowie durch Sonnenlicht und den Mond beeinflusst wird. Die Biologie reagiert auf die Verteilung von nahrhaften Chemikalien im Wasser, das in enger Wechselwirkung mit der Atmosphäre steht, von der Meeresoberfläche bis zur Stratosphäre. Bei jeder Fahrt wurde ein kleiner Teil der Myriaden von globalen und regionalen geheimen Wechselwirkungen, die die Grundlage unseres Lebens bestimmen, entdeckt und veröffentlicht. Das alte Zusammenspiel wird nun durch menschliche Aktivitäten stark beeinflusst. Ich hoffe, dass sie das wechselwirkende Gleichgewicht nicht kippen, so dass künftige Generationen weiterhin die Chance haben, es tiefer zu entschlüsseln, um nachhaltig damit leben zu können.

Meine letzte Fahrt konnte ich auf der RV Sonne, einem Starschiff der deutschen Forschungsflotte, mit einer professionellen Besatzung durchführen, die durch den reibungslosen Betrieb des Schiffes bis zum Hafen von Singapur wieder sehr gute Datensätze ermöglichte. In den nächsten Jahren werde ich vermutlich meine Datensätze hauptsächlich mit KI erforschen, um das meiste Wissen aus ihnen herauszuholen. Jule und Julia werden hoffentlich mehr Gelegenheiten finden, ihre Karriere mit Entdeckungsreisen auf dem Meer zu verbinden, da diese nicht nur Wissen fördern, sondern auch soziale Fähigkeiten wie Teamarbeit, Disziplin, Ausdauer, Rücksichtnahme und Toleranz entwickeln. Ich werde die täglichen Herausforderungen einer erfolgreichen Forschungsfahrt vermissen.
Birgit Quack, Singapur 18.05.2024
Ocean Acidification
METEOR Sets Sail on Its Final Voyage
Welcome to the M219 ocean blog!
Here, we will share updates and stories about the scientific work taking place during this research expedition. We also hope to offer a glimpse into daily life and work at sea.
For many members of the scientific party, this is their first time aboard METEOR. It will also be their last, as METEOR is embarking on its final voyage before retiring from service as a German research vessel after more than 40 years at sea. Over the course of its distinguished career, METEOR has travelled more than 1.7 million nautical miles, which is equivalent to more than 8 times the distance between the Earth and the Moon. Throughout those decades the vessel has supported countless scientific discoveries and generations of marine scientists. We are very grateful and honored to be part of the final chapter of this remarkable ship’s history and to accompany her on the last few thousand miles of her legendary journey.

The scientific program of this cruise focuses on long-term observations of ocean currents off the coast of Brazil and at the equator, as well as interdisciplinary measurements near the Cape Verde Islands. At all these sites, GEOMAR has maintained observational programs for the past 10 to 20 years. Over the next four weeks, we will introduce these regions and the measurements carried out there in more detail. But first, let’s look at what happened in Brazil before the cruise began.
On Thursday, May 28, many of the scientists and students left the hotel early in the morning to attend a seminar at the Universidade Federal de Pernambuco (UFPE), celebrating the long-standing scientific collaboration between Brazil and Germany.
The seminar was opened by Prof. Dr. Marius Müller, a former student at GEOMAR and now a professor for biological oceanography at UFPE. These meetings have become a valued tradition, having been organized for more than 20 years by now. This year marked the 9th edition of the seminar since its inception over 20 years ago.
A total of 8 scientists and students from Brazil, Germany, and the U.S. presented their research on various aspects of the tropical Atlantic Ocean. We would like to thank Marius Müller, Doris Veleda and all the Brazilian scientists and students who helped organize the seminar and provided such a warm welcome. We greatly enjoyed the exchange of ideas and look forward to celebrating the 10th seminar in the years to come.

After the seminar we returned to the hotel, but there was little time to rest. Later that same day, the captain of METEOR and the German Consul General in Recife hosted a reception aboard METEOR in the Port of Recife.
The event brought together members of the scientific party, representatives of local institutions, and guests from the Brazilian and German scientific communities. It provided an excellent opportunity to celebrate the long-standing partnership between the two countries.

On Friday, May 29, the scientific party finally boarded METEOR. There was little time to settle into our cabins and workspaces, as preparations for departure were already in full swing. We left the Port of Recife as soon as possible and at around 1pm METEOR set sail and began the final voyage of her remarkable career.
About 12 hours after leaving port, we arrived at our first station. Thanks to the dedicated efforts of technical and scientific teams, all instruments had been installed and prepared in time for the start of operations. This station marked the beginning of our observational program off the coast of Brazil, which includes the deployment and recovery of tall moorings as well as CTD measurements. An intensive first week lies ahead, with a demanding schedule of measurements and mooring operations. After months of planning and preparation, everyone is excited to finally begin the scientific work and make the most of the final weeks aboard METEOR.

Ocean Acidification
All About Gobies
There are more than 2,000 species of gobies (Gobiidae) known to science today, making them the largest family of fish in the ocean. But these small creatures are far more complex and essential to marine ecosystems than first meets the eye. Found all around the world in brackish, fresh and salt water in tropical and subtropical regions, they are an astonishingly diverse group of fish with several curious characteristics that set them apart.
Most gobies are quite small and don’t usually measure more than six inches long. Measuring just about eight millimeters long, the dwarf pygmy goby (Trimmatom nanus) is not only the tiniest goby known to science but also one of the smallest of all fish species in the world.
Primarily bottom-dwellers, gobies are known to be excellent foragers and have evolved expert burrowing behaviors over time. As they sift around looking for food like copepods, seaworms and tiny crustaceans, their movement helps to aerate sediment and keep algae in check. Some are even known to be “cleaner fish,” snacking on parasites they remove off larger creatures. It’s like a spa day for the animal being cleaned and a choose-your-own-adventure buffet for the gobies. Studies also show that cleaner goby activity is largely tied to the microbial health of coral reefs, showcasing that even the tiniest of species are essential to functioning marine ecosystems.
Gobies have some unique aspects to their anatomy, too. First, their fused pelvic fins are designed to help them form a strong suction cup to perch on coral reefs, rocks and other ocean terrain amidst turbulent currents. Some freshwater species are even known to use this suction to climb waterfalls. It may come as no surprise then that gobies are cousins to mudskippers, animals known to “walk” through mud. There are more species-specific features that set certain gobies apart. From the use of bioluminescence to symbiotic relationships with shrimp, the adaptations within the goby family are truly wide-ranging. Some species have even been found to use marine terrain memorization to navigate back to the tide pools where they were born. Isn’t nature mind-blowing sometimes?
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Gobies have equally complex and varied behaviors. Male gobies are infamous for being territorial protectors of their nests. Many larger males are known as “guarders;” these hopeful fish make careful nests to attract a mate, and once fertilization occurs, guarders will remain diligently near the nests to keep eggs safe. However, there’s another type of male goby that complicates this dynamic. These other males are known as “sneaker gobies” and are called that for one reason: They’re sneaky! If guarder gobies aren’t careful, sneakers can creep into the nest, fertilize some of the eggs and quickly escape. As if on an underwater episode of Maury, guarder males who aren’t careful could end up unknowingly babysitting little gobies that aren’t their actual offspring.
Gobies serve as indicators of ecological health and are essential to keeping delicate food webs in check. Unfortunately, many changes in our ocean threaten their ability to survive and thrive today. Coral bleaching and degradation endanger the health of one of their key habitats, and a combination of warming waters and coastal development can make it difficult for both juvenile and adult gobies to survive and thrive.
Healthy gobies mean a healthy ocean. Their essential role in marine ecosystems demonstrates that even the tiniest creatures play a major role in helping hold together the beautiful yet fragile habitats that make up our beloved ocean. Visit Ocean Conservancy’s Action Center and join the movement to protect our blue planet today and for years to come—from the tiniest goby to the largest whales, our ocean is counting on us.

The post All About Gobies appeared first on Ocean Conservancy.
Ocean Acidification
Do You Know the Difference Between El Niño and La Niña?
Recently, you may have heard about something called “El Niño.” But what exactly is El Niño and its sibling “La Niña”? Why do these terms seem to emerge from the depths of the scientific community and drop into popular vocabulary every few years? And how are they connected to extreme weather and our ocean?
What Are El Niño and La Niña?
El Niño and La Niña are part of a natural climate pattern in the tropical Pacific called the El Niño-Southern Oscillation, or ENSO. These two phases are different sides of the same coin, creating equally extreme shifts in temperature and air pressure.
El Niño occurs when surface water in the equatorial Pacific becomes warmer than average and easterly winds weaken. La Niña is the opposite: cooler-than-normal sea surface temperatures and stronger easterly winds. ENSO cycles can last up to seven years. El Niño and La Niña significantly impact weather patterns in all corners of the globe, often leading to more extreme weather, storm frequency and intensity.
A strong El Niño can cause flooding in some regions and drought, heat waves and wildfires in others. It often causes crop losses, coral bleaching and marine die-offs due to unusually warm ocean temperatures. El Niño tends to suppress Atlantic hurricane activity, though it increases the risk of heavy precipitation and harm to fisheries elsewhere. In the Northern Hemisphere, El Niño typically builds between March and June, peaks in December, and weakens by February.
La Niña, by contrast, often fuels an active Atlantic hurricane season and increases tornado frequency across the southern United States. Like El Niño, it builds in spring and peaks around December.
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Predicting ENSO
In 1923, the physicist Sir Gilbert Walker discovered the “Southern Oscillation,” or large-scale changes in sea level pressure across the tropical Pacific. However, it wasn’t until the late 1960s that the metorologist Jacob Bjerknes found that the changes in the ocean and the atmosphere were connected, and the hybrid term “ENSO” was born. In 1974, researchers at Oregon State University attempted to predict ENSO for the first time.
Modeling has greatly advanced since the early days. Today, scientists at the National Oceanic and Atmospheric Administration (NOAA) issue regular predictions about ENSO, which are now more accurate than ever.
NOAA gives a one-in-four chance that an El Niño could reach “very strong” intensity later in 2026, qualifying it as a “super El Niño.” This threshold has been crossed only a handful of times in recorded history, each triggering droughts, floods and record temperatures across multiple continents. NOAA’s data and models deliver life-saving early warning forecasts, like that of the predicted super El Niño, which allow communities to better prepare for and respond to extreme weather events.

Take Action
Every American, regardless of where they live, depends on NOAA’s scientists and professionals, whose work spans from the ocean floor to the far reaches of space. Unfortunately, NOAA is under threat. The Trump administration has proposed billions of dollars in cuts to the agency, which could weaken weather forecasting, disrupt fisheries management and stall critical ocean research, putting American lives and global scientific leadership at risk.
Ocean Conservancy is committed to working with NOAA to keep the public informed on climate and ocean science. We all benefit from a healthier ocean, and investing in research is the most effective way to restore ocean health and reduce the impact of severe weather events caused by El Niño and La Niña. Our ocean is not partisan, and protecting it requires all hands on deck and all sides of the aisle. Now, it’s more important than ever to demand that members of Congress prioritize our ocean. Add your name now.
The post Do You Know the Difference Between El Niño and La Niña? appeared first on Ocean Conservancy.
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