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von Dr. Birgit Quack, GEOMAR Helmholtz-Zentrum für Ozeanforschung Kiel

Es gibt zwei Bereiche in unserer Atmosphäre, in denen das Spurengas Ozon besonders wichtig ist: in der Stratosphäre und in der Grenzschicht an der Erdoberfläche. In der oberen Region unserer Atmosphäre, der Stratosphäre, entsteht Ozon durch den Zerfall von Sauerstoff im Sonnenlicht und wirkt als wichtiger UV-Strahlenschutz für das Leben auf der Erde. Es wird durch Radikalreaktionen von Halogenen wie Chlor, Brom und Jod, die in verschiedenen Formen in unserer Atmosphäre vorkommen, rasch zerstört. In den 1980er Jahren trat ein großes Ozonloch auf, das mit den langlebigen Fluorchlorkohlenwasserstoffen in Verbindung gebracht werden konnte, die in den 1990er Jahren durch das Montrealer Protokoll verboten wurden. Seitdem nehmen das Ozonloch über der Antarktis und das Ozon in der oberen Stratosphäre im Allgemeinen langsam wieder zu. In der unteren Stratosphäre der Tropen nimmt es jedoch weiterhin ab. Das Oberflächenozon hingegen nimmt zu, was auf die Luftverschmutzung zurückzuführen ist, insbesondere auf die Verbrennung fossiler Brennstoffe.

Abb.1: Oberflächenozon am Sonntag, 12. Mai, 14 Uhr Ortszeit (7 Uhr UTC). (windy.com)

Unter windy.com kann jeder weltweit, der Zugang zum Internet hat, eine globale Karte von Oberflächenozon und lokale Werte für jeden Ort der Welt finden (Abbildung 1). Oberflächenozon, das auch ein Treibhausgas ist, wird auf natürliche Weise bis zu einer Hintergrundkonzentration von 10-40 µg/m3 produziert. Da es ein starkes Oxidationsmittel ist, kann es in höheren Konzentrationen Augen und Lunge reizen. Für Städte, in denen die Umgebungskonzentrationen im Sommer über 100 µg/m3 ansteigen und empfindliche Menschen schädigen können, wurden gesetzliche Grenzwerte und Warnsysteme eingerichtet.

Abbildung 1 zeigt die Ozonkonzentration an der Oberfläche in dem Gebiet, in dem unsere Fahrt SO305 im Golf von Bengalen stattfand. Sie ist tagsüber über ganz Indien sehr hoch, und es ist auch offensichtlich, dass die Ozonkonzentrationen an den Küsten und zum offenen Ozean hin stark abnehmen. Dies ist hauptsächlich auf eine aktive Halogenchemie zurückzuführen, die das Ozon über den Ozeanen zerstört, verursacht durch natürliche halogenierte flüchtige Verbindungen, die in den Ozeanen durch Sonnenlicht, Phytoplankton und chemische Reaktionen gebildet werden. Zu diesen Verbindungen gehören Bromoform (CHBr3), Dibrommethan (CH2Br2), Methyljodid (CH3I), Dijodmethan (CH2I2), Jodchlormethan (CH2CII), Dichlorbrommethan (CHBrCl2) und andere. Sie gelangen in die Atmosphäre und setzen dort Halogene frei, die mit Ozon reagieren. Alle Verbindungen haben eine kurze Lebensdauer von Minuten bis zu weniger als sechs Monaten. Die industriellen Lösungsmittel Dichlormethan (CH2Cl2) und Chloroform (CHCl3) aus der Süßwasserchlorierung tragen ebenfalls zum Ozonabbau in der Atmosphäre bei. Die Verbindungen, die durch tiefe Konvektion in den Tropen in die Stratosphäre gehoben werden, setzen ihre Halogene in der unteren Stratosphäre frei, während sie sich zum Nord- und Südpol bewegen. So wirken sich die tropischen Prozesse global aus.

In den letzten vier Wochen waren wir nun im tropischen Golf von Bengalen, der 2001 als Hauptquelle für einige natürliche halogenierte flüchtige Verbindungen für die Atmosphäre entdeckt wurde, mit RV Sonne unterwegs.

Gaschromatographisch-massenspektrometrisches (GC/MS) Spülsystem zur Messung von flüchtigen halogenierten Kohlenwasserstoffen in Meer und Atmosphäre. Jule Ploschke, Julia Mickenbecker und Birgit Quack mit Wasser- und Luftprobenahmegeräten. (Foto: Hendrick Feil)

Jule, die ihre Masterarbeit zu diesem Thema schreibt, Julia, die zum zweiten Mal als studentische Hilfskraft auf der RV Sonne mitfährt und ich, die seit über 30 Jahren auf den Weltmeeren flüchtige Halogenkohlenwasserstoffe untersucht, brachten unser Analysesystem mit an Bord, das seit Beginn der Fahrt rund um die Uhr in Schichten von jeweils 8 Stunden reibungslos lief, wobei das Gerät jede Stunde eine neue Probe erhält. Wir haben Wasser aus der Tiefsee und dem Oberflächenozean und Luft aus der Atmosphäre entnommen (Abbildung 3). Die Luftproben werden von Elliot Atlas in den USA analysiert, mit dem ich seit 2002 in 15 Kampagnen zusammengearbeitet habe. Aus den Konzentrationen im Ozean und in der Atmosphäre berechnen wir den Gasaustausch zwischen Luft und Meer, und versuchen zu verstehen, wie die Verbindungen in der Region mit physikalischen und biogeochemischen Parametern zusammenhängen, und schätzen ab, wie sich die ozeanische Quelle und Senke in Zukunft entwickeln könnten und was dies für Ozon als Treibhausgas und als UV-Schild bedeutet.

Bei jeder Schiffsexpedition in den 30 Jahren, in denen wir die Ozeane bereisten, erforschte ein Team von Wissenschaftlern und Crew an Bord verschiedener Forschungsschiffe den Ozean als ein uraltes Zusammenspiel von Wasser, Chemikalien, Billionen von Bakterien und höheren Organismen, das durch die Schwerkraft, die Erdrotation sowie durch Sonnenlicht und den Mond beeinflusst wird. Die Biologie reagiert auf die Verteilung von nahrhaften Chemikalien im Wasser, das in enger Wechselwirkung mit der Atmosphäre steht, von der Meeresoberfläche bis zur Stratosphäre. Bei jeder Fahrt wurde ein kleiner Teil der Myriaden von globalen und regionalen geheimen Wechselwirkungen, die die Grundlage unseres Lebens bestimmen, entdeckt und veröffentlicht. Das alte Zusammenspiel wird nun durch menschliche Aktivitäten stark beeinflusst. Ich hoffe, dass sie das wechselwirkende Gleichgewicht nicht kippen, so dass künftige Generationen weiterhin die Chance haben, es tiefer zu entschlüsseln, um nachhaltig damit leben zu können.

Die letzte Luftprobe auf SO305. (Foto: Hermann Bange)

Meine letzte Fahrt konnte ich auf der RV Sonne, einem Starschiff der deutschen Forschungsflotte, mit einer professionellen Besatzung durchführen, die durch den reibungslosen Betrieb des Schiffes bis zum Hafen von Singapur wieder sehr gute Datensätze ermöglichte. In den nächsten Jahren werde ich vermutlich meine Datensätze hauptsächlich mit KI erforschen, um das meiste Wissen aus ihnen herauszuholen. Jule und Julia werden hoffentlich mehr Gelegenheiten finden, ihre Karriere mit Entdeckungsreisen auf dem Meer zu verbinden, da diese nicht nur Wissen fördern, sondern auch soziale Fähigkeiten wie Teamarbeit, Disziplin, Ausdauer, Rücksichtnahme und Toleranz entwickeln. Ich werde die täglichen Herausforderungen einer erfolgreichen Forschungsfahrt vermissen.

Birgit Quack, Singapur 18.05.2024

Hallo Halos in und über der Bay of Bengal

Ocean Acidification

What is the High Seas Treaty and Why Does It Matter?

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You may have seen headlines recently about a new global treaty that went into effect just as news broke that the United States would be withdrawing from a number of other international agreements. It’s a confusing time in the world of environmental policy, and Ocean Conservancy is here to help make it clearer while, of course, continuing to protect our ocean.

What is the High Seas Treaty?

The “High Seas Treaty,” formally known as the Agreement on the Conservation and Sustainable Use of Marine Biological Diversity of Areas Beyond National Jurisdiction (BBNJ) Agreement, went into effect on January 17, 2026. We celebrated this win last fall, when the agreement reached the 60 ratifications required for its entry into force. (Since then, an additional 23 countries have joined!) It is the first comprehensive international legal framework dedicated to addressing the conservation and sustainable use of the high seas (the area of the ocean that lies 200 miles beyond the shorelines of individual countries).

To “ensure the conservation and sustainable use of marine biological diversity” of these areas, the BBNJ addresses four core pillars of ocean governance:

  1. Marine genetic resources: The high seas contain genetic resources (genes of plants, animals and microbes) of great value for pharmaceuticals, cosmetics and food production. The treaty will ensure benefits accrued from the development of these resources are shared equitably amongst nations.
  2. Area-based management tools such as the establishment of marine protected areas (MPAs) in international waters. Protecting important areas of the ocean is essential for healthy and resilient ecosystems and marine biodiversity.
  3. Environmental impact assessments (EIA) will allow us to better understand the potential impacts of proposed activities that may harm the ocean so that they can be managed appropriately.
  4. Capacity-building and the transfer of marine technology with particular emphasis on supporting developing states. This section of the treaty is designed to ensure all nations benefit from the conservation and sustainable use of marine biodiversity through, for example, the sharing of scientific information.

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Why is the High Seas Treaty Important?

The BBNJ agreement is legally binding for the countries that have ratified it and is the culmination of nearly two decades of negotiations. Its enactment is a historic milestone for global ocean governance and a significant advancement in the collective protection of marine ecosystems.

The high seas represent about two-thirds of the global ocean, and yet less than 10% of this area is currently protected. This has meant that the high seas have been vulnerable to unregulated or illegal fishing activities and unregulated waste disposal. Recognizing a major governance gap for nearly half of the planet, the agreement puts in place a legal framework to conserve biodiversity.

A map of the globe depicting the areas designated as high seas versus exclusively an economic zone. The high seas represent about two-thirds of the global ocean.

As it promotes strengthened international cooperation and accountability, the agreement will establish safeguards aimed at preventing and reversing ocean degradation and promoting ecosystem restoration. Furthermore, it will mobilize the international community to develop new legal, scientific, financial and compliance mechanisms, while reinforcing coordination among existing treaties, institutions and organizations to address long-standing governance gaps.

How is Ocean Conservancy Supporting the BBNJ Agreement?

Addressing the global biodiversity crisis is a key focal area for Ocean Conservancy, and the BBNJ agreement adds important new tools to the marine conservation toolbox and a global commitment to better protect the ocean.

Ocean Conservancy’s efforts to protect the “ocean twilight zone”—an area of the ocean 200-1000m (600-3000 ft) below the surface—is a good example of why the BBNJ agreement is so important. The ocean twilight zone (also known as the mesopelagic zone) harbors incredible marine biodiversity, regulates the climate and supports the health of ocean ecosystems. By some estimates, more than 90% of the fish biomass in the ocean resides in the ocean twilight zone, attracting the interest of those eager to develop new sources of protein for use in aquaculture feed and pet foods.

An illustration of the zones of the ocean floor, depicting depth in meters/feet on the left and the layers from light blue to dark blue and orange, listed as follows: Continental Shelf (Epipelagic Zone: The Sunlight Zone; Mesopelagic Zone: The Twilight Zone), Continental Slope (Bathypelagic Zone: The Midnight Zone); Continental Rise (Abyssopelagic Zone: The Abyss), Ocean Basin, Hadal Zone: The Trenches.

Done poorly, such development could have major ramifications for the health of our planet, jeopardizing the critical role these species play in regulating the planet’s climate and sustaining commercially and ecologically significant marine species. Species such as tunas (the world’s most valuable fishery), swordfish, salmon, sharks and whales depend upon mesopelagic species as a source of food. Mesopelagic organisms would also be vulnerable to other proposed activities including deep-sea mining.

A significant portion of the ocean twilight zone is in the high seas, and science and policy experts have identified key gaps in ocean governance that make this area particularly vulnerable to future exploitation. The BBNJ agreement’s provisions to assess the impacts of new activities on the high seas before exploitation begins (via EIAs) as well as the ability to proactively protect this area can help ensure the important services the ocean twilight zone provides to our planet continue well into the future.

What’s Next?

Notably, the United States has not ratified the treaty, and, in fact, just a few days before it went into effect, the United States announced its withdrawal from several important international forums, including many focused on the environment. While we at Ocean Conservancy were disappointed by this announcement, there is no doubt that the work will continue.

With the agreement now in force, the first Conference of the Parties (COP1), also referred to as the BBNJ COP, will convene within the next year and will play a critical role in finalizing implementation, compliance and operational details under the agreement. Ocean Conservancy will work with partners to ensure implementation of the agreement is up to the challenge of the global biodiversity crisis.

The post What is the High Seas Treaty and Why Does It Matter? appeared first on Ocean Conservancy.

https://oceanconservancy.org/blog/2026/02/25/high-seas-treaty/

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Ocean Acidification

Hälsningar från Åland och Husö biological station

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On Åland, the seasons change quickly and vividly. In summer, the nights never really grow dark as the sun hovers just below the horizon. Only a few months later, autumn creeps in and softly cloaks the island in darkness again. The rhythm of the seasons is mirrored by the biological station itself; researchers, professors, and students arrive and depart, bringing with them microscopes, incubators, mesocosms, and field gear to study the local flora and fauna peaking in the mid of summer.

This year’s GAME project is the final chapter of a series of studies on light pollution. Together, we, Pauline & Linus, are studying the effects of artificial light at night (ALAN) on epiphytic filamentous algae. Like the GAME site in Japan, Akkeshi, the biological station Husö here on Åland experiences very little light pollution, making it an ideal place to investigate this subject.

We started our journey at the end of April 2025, just as the islands were waking up from winter. The trees were still bare, the mornings frosty, and the streets quiet. Pauline, a Marine Biology Master’s student from the University of Algarve in Portugal, arrived first and was welcomed by Tony Cederberg, the station manager. Spending the first night alone on the station was unique before the bustle of the project began.

Linus, a Marine Biology Master’s student at Åbo Akademi University in Finland, joined the next day. Husö is the university’s field station and therefore Linus has been here for courses already. However, he was excited to spend a longer stretch at the station and to make the place feel like a second home.

Linus & Pauline on Husö (left) and our home for the summer season on Husö, Nya Villan (right). (c) Pauline Wasle.

Our first days were spent digging through cupboards and sheds, reusing old materials and tools from previous years, and preparing the frames used by GAME 2023. We chose Hamnsundet as our experimental site, (i.e. the same site that was used for GAME 2023), which is located at the northeast of Åland on the outer archipelago roughly 40 km from Husö. We got permission to deploy the experiments by the local coast guard station, which was perfect. The location is sheltered from strong winds, has electricity access, can be reached by car, and provides the salinity conditions needed for our macroalga, Fucus vesiculosus, to survive.

Sanding PVC plates and cleaning the frames from two years ago. (c) left Linus Holmlund and (c) right Pauline Wasle.

To assess the conditions at the experimental site, we deployed a first set of settlement panels in late April. At first, colonization was slow; only a faint biofilm appeared within two weeks. With the water temperature being still around 7 °C, we decided to give nature more time. Meanwhile, we collected Fucus individuals and practiced the cleaning and the standardizing of the algal thalli for the experiment. Scraping epiphytes off each thallus piece was fiddly, and agreeing on one method was crucial to make sure our results would be comparable to those of other GAME teams.

PVC settlement panel with a faint biofilm, two weeks after deployment. (c) Pauline Wasle.

By early May, building the light setup was a project in itself. Sawing, drilling, testing LEDs, and learning how to secure a 5-meter wooden beam over the water. Our first version bent and twisted until the light pointed sideways instead of straight down onto the algae. Only after buying thicker beams and rebuilding the structure, we finally got a stable and functional setup that could withstand heavy rain and wind. The day we deployed our first experiment at Hamnsundet was cold and rainy but also very rewarding!

Testing a possible experimental setup in the lab ((c) left Pauline Wasle) and the final setup in the field ((c) right Walter Thörnwall).
Finally in the water: Our experimental setup including 4 frames with algal substrates and PVC strips. Two wooden beams were equipped with lighting systems. (c) Tim Wasle.

Outside of work, we made the most of the island life. We explored Åland by bike, kayak, rowboat, and hiking, visited Ramsholmen National Park during the ramson/ wild garlic bloom, and hiked in Geta with its impressive rock formations and went out boating and fishing in the archipelago. At the station on Husö, cooking became a social event: baking sourdough bread, turning rhubarb from the garden into pies, grilling and making all kind of mushroom dishes. These breaks, in the kitchen and in nature, helped us recharge for the long lab sessions to come.

Rock formations in Geta, a famous bouldering spot on Åland. (c) Pauline Wasle.

Every two weeks, it was time to collect and process samples. Snorkeling to the frames, cutting the Fucus and the PVC plates from the lines, and transferring each piece into a freezer bag became our routine. Sampling one experiment took us 4 days and processing all the replicates in the lab easily filled an entire week. The filtering and scraping process was even more time-consuming than we had imagined. It turned out that epiphyte soup is quite thick and clogs filters fastly. This was frustrating at times, since it slowed us down massively.

Over the months, the general community in the water changed drastically. In June, water was still at 10 °C, Fucus carried only a thin layer of diatoms and some very persistent and hard too scrape brown algae (Elachista). In July, everything suddenly exploded: green algae, brown algae, diatoms, cyanobacteria, and tiny zooplankton clogged our filters. With a doubled filtering setup and 6 filtering units, we hoped to compensate for the additional growth.

However, what we had planned as “moderate lab days” turned into marathon sessions. In August, at nearly 20 °C, the Fucus was looking surprisingly clean, but on the PVC a clear winner had emerged. The panels were overrun with the green alga Ulva and looked like the lawn at an abandoned house. Here it was not enough to simply filter the solution, but bigger pieces had to be dried separately. In September, we concluded the last experiment with the help of Sarah from the Cape Verde team, as it was not possible for her to continue on São Vicente, the Cape Verdean island that was most affected by a tropical storm. Our final experiment brought yet another change into community now dominated by brown algae and diatoms. Thankfully our new recruit, sunny autumn weather, and mushroom picking on the side made the last push enjoyable.

Fucus vesiculosus from experiment 3 (top left), Fucus vesiculosus from experiment 4 (top right), PVC from experiment 1 (bottom left) and PVC from experiment 3 (bottom right). (c) Linus Holmlund.

By the end of summer, we had accomplished four full experiments. The days were sometimes exhausting but also incredibly rewarding. We learned not only about the ecological effects of artificial light at night, but also about the very practical side of marine research; planning, troubleshooting, and the patience it takes when filtering a few samples can occupy half a day.

Mushrooms for dinner found right at our experimental site in Hamnsundet. (c) Pauline Wasle.

Hälsningar från Åland och Husö biological station

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Ocean Acidification

What is Coral Bleaching and Why is it Bad News for Coral Reefs?

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Coral reefs are beautiful, vibrant ecosystems and a cornerstone of a healthy ocean. Often called the “rainforests of the sea,” they support an extraordinary diversity of marine life from fish and crustaceans to mollusks, sea turtles and more. Although reefs cover less than 1% of the ocean floor, they provide critical habitat for roughly 25% of all ocean species.

Coral reefs are also essential to human wellbeing. These structures reduce the force of waves before they reach shore, providing communities with vital protection from extreme weather such as hurricanes and cyclones. It is estimated that reefs safeguard hundreds of millions of people in more than 100 countries. 

What is coral bleaching?

A key component of coral reefs are coral polyps—tiny soft bodied animals related to jellyfish and anemones. What we think of as coral reefs are actually colonies of hundreds to thousands of individual polyps. In hard corals, these tiny animals produce a rigid skeleton made of calcium carbonate (CaCO3). The calcium carbonate provides a hard outer structure that protects the soft parts of the coral. These hard corals are the primary building blocks of coral reefs, unlike their soft coral relatives that don’t secrete any calcium carbonate.

Coral reefs get their bright colors from tiny algae called zooxanthellae. The coral polyps themselves are transparent, and they depend on zooxanthellae for food. In return, the coral polyp provides the zooxanethellae with shelter and protection, a symbiotic relationship that keeps the greater reefs healthy and thriving.

When corals experience stress, like pollution and ocean warming, they can expel their zooxanthellae. Without the zooxanthellae, corals lose their color and turn white, a process known as coral bleaching. If bleaching continues for too long, the coral reef can starve and die.


Ocean warming and coral bleaching

Human-driven stressors, especially ocean warming, threaten the long-term survival of coral reefs. An alarming 77% of the world’s reef areas are already affected by bleaching-level heat stress.

The Great Barrier Reef is a stark example of the catastrophic impacts of coral bleaching. The Great Barrier Reef is made up of 3,000 reefs and is home to thousands of species of marine life. In 2025, the Great Barrier Reef experienced its sixth mass bleaching since 2016. It should also be noted that coral bleaching events are a new thing because of ocean warming, with the first documented in 1998.

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How you can help

The planet is changing rapidly, and the stakes have never been higher. The ocean has absorbed roughly 90% of the excess heat caused by anthropogenic greenhouse gas emissions, and the consequences, including coral die-offs, are already visible. With just 2℃ of planetary warming, global coral reef losses are estimated to be up to 99% — and without significant change, the world is on track for 2.8°C of warming by century’s end.

To stop coral bleaching, we need to address the climate crisis head on. A recent study from Scripps Institution of Oceanography was the first of its kind to include damage to ocean ecosystems into the economic cost of climate change – resulting in nearly a doubling in the social cost of carbon. This is the first time the ocean was considered in terms of economic harm caused by greenhouse gas emissions, despite the widespread degradation to ocean ecosystems like coral reefs and the millions of people impacted globally.

This is why Ocean Conservancy advocates for phasing out harmful offshore oil and gas and transitioning to clean ocean energy. In this endeavor, Ocean Conservancy also leads international efforts to eliminate emissions from the global shipping industry—responsible for roughly 1 billion tons of carbon dioxide every year.

But we cannot do this work without your help. We need leaders at every level to recognize that the ocean must be part of the solution to the climate crisis. Reach out to your elected officials and demand ocean-climate action now.

The post What is Coral Bleaching and Why is it Bad News for Coral Reefs? appeared first on Ocean Conservancy.

What is Coral Bleaching and Why is it Bad News for Coral Reefs?

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